Over 17% Efficiency Stand-Alone Solar Water Splitting Enabled by Perovskite-Silicon Tandem Absorbers

Date

2020

Authors

Karuturi, Siva Krishna
Shen, Heping
Sharma, Astha
Beck, Fiona
Varadhan, Purushothaman
Duong, The
Narangari, Parvathala
Zhang, Doudou
Wan, Yimao
He, Jr-Hau

Journal Title

Journal ISSN

Volume Title

Publisher

Wiley - VCH Verlag GmbH & CO. KGaA

Abstract

Realizing solar‐to‐hydrogen (STH) efficiencies close to 20% using low‐cost semiconductors remains a major step toward accomplishing the practical viability of photoelectrochemical (PEC) hydrogen generation technologies. Dual‐absorber tandem cells combining inexpensive semiconductors are a promising strategy to achieve high STH efficiencies at a reasonable cost. Here, a perovskite photovoltaic biased silicon (Si) photoelectrode is demonstrated for highly efficient stand‐alone solar water splitting. A p+nn+ ‐Si/Ti/Pt photocathode is shown to present a remarkable photon‐to‐current efficiency of 14.1% under biased condition and stability over three days under continuous illumination. Upon pairing with a semitransparent mixed perovskite solar cell of an appropriate bandgap with state‐of‐the‐art performance, an unprecedented 17.6% STH efficiency is achieved for self‐driven solar water splitting. Modeling and analysis of the dual‐absorber PEC system reveal that further work into replacing the noble‐metal catalyst materials with earth‐abundant elements and improvement of perovskite fill factor will pave the way for the realization of a low‐cost high‐efficiency PEC system.

Description

Keywords

hydrogen generation, perovskite solar cells, photoelectrochemical cell, Si photoelectrodes, stand‐alone water splitting

Citation

Source

Advanced Energy Materials

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

Restricted until

2099-12-31