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Mononuclear Co(III) and Ni(II) Complexes with Polypyridyl Ligands, [Co(phen) 2 (taptp)] 3+ and [Ni(phen) 2 (taptp)] 2+ : Synthesis, Photocleavage and DNA-binding

Date

Authors

Morshedi, Mahbod

Hadadzadeh, Hassan

Publisher

Kluwer Academic/Plenum Publishers

Abstract

Two novel, mixed ligand complexes of cobalt(III) and nickel(II), [Co(phen)2(taptp)]3+ (1) and [Ni(phen)2(taptp)] 2+ (2) (phen = 1,10-phenanthroline and taptp = 4,5,9,18- tetraazaphenanthreno [9,10-b]triphenylene), were synthesized and characterized by ele

Keywords

Keywords: DNA binding; Intercalative mode; Mixed-ligands; Ni complexes; Photocleavages; Polypyridyl ligands; Binding energy; Complexation; DNA; Electrophoresis; Emission spectroscopy; Ligands; Nickel; Nuclear magnetic resonance spectroscopy; Spectroscopic analysis; Co (III) and Ni(II) complexes; DNA binding; Intercalative mode; Mixed-ligand; Photocleavage; Polypyridyl ligands

URI

http://hdl.handle.net/1885/25816

Collections

ANU Research Publications

Source

Journal of Fluorescence

Type

Journal article

DOI

10.1007/s10895-012-1143-0

Restricted until

2037-12-31

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Description

01_Morshedi_Mononuclear_Co(III)_and_Ni(II)_2013.pdf (305.68 KB)