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Is the Addition-Fragmentation Step of the RAFT Polymerisation Process Chain Length Dependent?

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Authors

Izgorodina, Ekaterina
Coote, Michelle

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Wiley-VCH Verlag GMBH

Abstract

The chain length dependence of the addition-fragmentation equilibrium constant (K) for cumyl dithiobenzoate (CDB) mediated polymerisation of styrene has been studied via high level ab initio molecular orbital calculations. The results indicate that chain

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Macromolecular Theory and Simulations

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Restricted until

2037-12-31