Homoanomeric effect in the 1,2-dimethoxyethyl radical

Date

2003

Authors

Henry, David
Beckmann, Annalise
Radom, Leo

Journal Title

Journal ISSN

Volume Title

Publisher

CSIRO Publishing

Abstract

A homoanomeric effect is found to stabilize the 1,2-dimethoxyethyl radical (CH3O-C•H-CH2OCH3) in a conformation in which the singly-occupied orbital at the radical centre is approximately coplanar with the p-type lone pair on the α-oxygen and with the

Description

Keywords

Keywords: Chemical bonds; Conformations; Free radicals; Molecular orientation; Numerical analysis; Photoelectron spectroscopy; Dimethoxyethyl radical; Homoanomeric effect; Molecular orbital; Hydrocarbons

Citation

Source

Australian Journal of Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1071/CH02255

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