Alkynylselenolatoalkylidynes: [Mo(≡CSeC≡CR)(CO) 2 {HB(pzMe 2 ) 3 }] (R = CMe 3 , SiMe 3 ; pzMe 2 = 3,5-Dimethylpyrazol-1-yl)

Date

2008

Authors

Caldwell, Lorraine
Hill, Anthony
Rae, A David
Willis, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The reactions of [Mo(≡CCI)(CO)2{HB(pzMe2) 3]] (pz = 3,5-dimethylpyrazol-1-yl) with lithium alkynylselenolates (LiSeC=CR; R = CMe3, SiMe3) provide the alkynylselenolatoalkylidyne complexes [Mo(≡CSeC≡CR)(CO) 2{HB(pzMe2)3}]. Cobalt carbonyl adds across

Description

Keywords

Keywords: Complexation; Alkynylselenolatoalkylidynes; Aromatic compounds

Citation

Source

Organometallics

Type

Journal article

Book Title

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Restricted until

2037-12-31