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An hermaphrodite [2]rotaxane: preparation and analysis of structure

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Onagi, Hideki
Easton, Christopher
Lincoln, Stephen F

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American Chemical Society

Abstract

(matrix presented) The pictured rotaxane is assembled in water by capping a substituted cyclodextrin composed of the wheel and axle components. The unusual dimeric structure of the rotaxane reflects the thermodynamics of the assembly process. In N,N-dimethylformamide, the corresponding monomer is the predominant product.

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Organic Letters

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Restricted until

2037-12-31