Theoretical analysis of the [Mn 2 (m-oxo) 2 (m-carboxylato) 2 ] + core

Abstract

The first example of a dinuclear manganese complex containing two oxo and two carboxylate bridges. [Mn2 (μ-O)2(μ-O 2CArTol)2(bpy)2]+ (where bpy = 2,2′-bipyridine, and ArTolCO2 = 2,6-di(p-tolyl)benzoate), was reported recently (J. Am. Chem. Soc. 2003, Show more