Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Mixed-metal cluster chemistry Part 20. Syntheses, crystal structures and electrochemical studies of W 2 Ir 2 (u-L)(CO) 8 (η 5 -C 5 H 4 Me) 2 (L = dppe, dppf)

Date

Authors

Blitz, Jonathan

Lucas, Nigel

Humphrey, Mark

Publisher

Elsevier

Abstract

The 60-electron tetrahedral clusters W2Ir2(μ-L)(CO)8(η5-C5H4Me)2 [L = dppe (2), dppf (3)] have been prepared from reaction between W2Ir2 (CO)10(η5-C5H4Me)2 (1) and the corresponding diphosphine in 52 amd 66% yields, respectively. A structiral study of

Keywords

Keywords: carbonyl derivative; iridium; ligand; metal; methyl group; phosphine derivative; tungsten derivative; chemical bond; chemical reaction; controlled study; crystal structure; electrochemistry; electron; energy; oxidation; review; synthesis; ultraviolet spec Carbonyl; Cluster; Cyclopentadienyl; Iridium; Phosphine; Tungsten

URI

http://hdl.handle.net/1885/92391

Collections

ANU Research Publications

Source

Journal of Organometallic Chemistry

Type

Journal article

DOI

10.1016/S0022-328X(02)01201-9

Restricted until

2037-12-31

Downloads

File

Description

01_Blitz_Mixed-metal_cluster_chemistry_2002.pdf (439.99 KB)