Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap
dc.contributor.author | Xu, Qinke | |
dc.contributor.author | Jiang, Xingxing | |
dc.contributor.author | Wu, Chao | |
dc.contributor.author | Lin, Lin | |
dc.contributor.author | Huang, Zhipeng | |
dc.contributor.author | Lin, Zheshuai | |
dc.contributor.author | Humphrey, Mark | |
dc.contributor.author | Zhang, Chi | |
dc.date.accessioned | 2022-11-01T02:55:04Z | |
dc.date.issued | 2021 | |
dc.date.updated | 2021-11-28T07:25:43Z | |
dc.description.abstract | Ultraviolet (UV) nonlinear optical (NLO) materials possess important practical applications in modern laser science and technology, which are attracting significant research interest in the fields of chemistry, physics and materials science. A fluorinated mixed main-group metal sulfate and its defluorinated analogue, Rb InF (SO ) (RIFSO) and Rb In(SO ) (RISO), were designed and synthesized for NLO studyviamild hydrothermal methods. RIFSO unfortunately crystallizes in centric space groupPbcn(no. 60) while RISO crystallizes in acentric space groupR3c(no. 161). Both of them exhibit a one-dimensional chain structure composed of corner-shared [InO F ] or [InO ] and [SO ] groups. Optical property studies reveal that RISO displays a large band gap (5.75 eV) corresponding to a short UV cut-off edge (215 nm), a moderate second harmonic generation (SHG) efficiency of ∼0.5 times that of KH PO (KDP) with phase-matchable performance, and high thermostability (>800 °C), demonstrating its potential as an applicable UV NLO material. First-principles calculations have been performed to further elucidate the structure-property relationship of RISO. | en_AU |
dc.description.sponsorship | This research was financially supported by the National Natural Science Foundation of China (No. 51432006 and 51172100), the Ministry of Education of China for the Changjiang Innovation Research Team (No. IRT14R23), the Ministry of Education and the State Administration of Foreign Experts Affairs for the 111 Project (No. B13025), the Innovation Program of Shanghai Municipal Education Commission, and the National and Shanghai Postdoctoral Program for Innovative Talents (no. BX201800216 and 2018192). M. G. H. and C. Z. thank the Australian Research Council for support. | en_AU |
dc.format.mimetype | application/pdf | en_AU |
dc.identifier.issn | 2050-7534 | en_AU |
dc.identifier.uri | http://hdl.handle.net/1885/277341 | |
dc.language.iso | en_AU | en_AU |
dc.publisher | Royal Society of Chemistry | en_AU |
dc.rights | © 2021 The authors | en_AU |
dc.source | Journal of Materials Chemistry C | en_AU |
dc.title | Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap | en_AU |
dc.type | Journal article | en_AU |
local.bibliographicCitation.issue | 15 | en_AU |
local.bibliographicCitation.lastpage | 5131 | en_AU |
local.bibliographicCitation.startpage | 5124 | en_AU |
local.contributor.affiliation | Xu, Qinke, Tongji University | en_AU |
local.contributor.affiliation | Jiang, Xingxing, Chinese Academy of Sciences | en_AU |
local.contributor.affiliation | Wu, Chao, Tongji University | en_AU |
local.contributor.affiliation | Lin, Lin, Tongji University | en_AU |
local.contributor.affiliation | Huang, Zhipeng, Tongji University | en_AU |
local.contributor.affiliation | Lin, Zheshuai, Chinese Academy of Sciences | en_AU |
local.contributor.affiliation | Humphrey, Mark, College of Science, ANU | en_AU |
local.contributor.affiliation | Zhang, Chi, Tongji University | en_AU |
local.contributor.authoremail | u9400918@anu.edu.au | en_AU |
local.contributor.authoruid | Humphrey, Mark, u9400918 | en_AU |
local.description.embargo | 2099-12-31 | |
local.description.notes | Imported from ARIES | en_AU |
local.identifier.absfor | 000000 - Internal ANU use only | en_AU |
local.identifier.ariespublication | a383154xPUB19300 | en_AU |
local.identifier.citationvolume | 9 | en_AU |
local.identifier.doi | 10.1039/d1tc00383f | en_AU |
local.identifier.scopusID | 2-s2.0-85104622908 | |
local.identifier.uidSubmittedBy | a383154 | en_AU |
local.publisher.url | https://pubs.rsc.org/ | en_AU |
local.type.status | Published Version | en_AU |
Downloads
Original bundle
1 - 1 of 1
No Thumbnail Available
- Name:
- Rb3In (SO4)3.pdf
- Size:
- 2.62 MB
- Format:
- Adobe Portable Document Format
- Description: