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Synthesis, X-ray structure and electrochemical oxidation of palladium(II) complexes of ferrocenyldiphenylphosphine

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Date

2010

Authors

Bennett, Martin
Bhargava, Suresh Kumar
Bond, Alan M
Burgar, Iko M
Guo, Si-Xuan
Kar, Gopa
Priver, Steven H
Wagler, Jorg
Willis, Anthony
Torriero, Angel AJ

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

Four new complexes, [PdX(κ2-2-C6R 4PPh2)(PPh2Fc)] [X = Br, R = H (1), R = F (2); X = I, R = H (3), R = F (4)], containing ferrocenyldiphenylphosphine (PPh 2Fc) have been prepared and fully characterised. The X-ray structures of complexes trans-1, cis-2 a

Description

Keywords

Keywords: Bulk electrolysis; Chelate ligands; Decomposition products; Electrochemical reactions; Ferrocenes; Metal atoms; Metal-phosphorus bonds; Palladium complexes; Positive potential; Rotating disk voltammetry; Square planar geometry; UV-visible spectroelectroch

Citation

URI

http://hdl.handle.net/1885/57657

Collections

ANU Research Publications

Source

Dalton Transactions

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/c0dt00016g

Restricted until

2037-12-31

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01_Bennett_Synthesis,_X-ray_structure_and_2010.pdf (651.91 KB)

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