Aryne Complexes of Zerovalent Metals of the Nickel Triad

Date

Authors

Bennett, Martin

Publisher

CSIRO Publishing

Abstract

The chemistry of dihapto-aryne complexes of the zerovalent Group 10 metals of general formula [M(η2-aryne)L2] (M = Ni, Pd, Pt; L = various tertiary phosphines) is reviewed, with emphasis on the highly reactive nickel(0) compounds (aryne = benzyne, C6H4;

Keywords

Keywords: Alkynyls; Benzyne; Benzyne complexes; Boronic acid; Electron donors; Metal bonds; Nickel atoms; Nickel halides; Orthometallation; Oxidative additions; Polycyclic compounds; Reductive elimination; Sequential insertion; Suzuki-Miyaura coupling; Tertiary pho

URI

http://hdl.handle.net/1885/60177

Collections

ANU Research Publications

Source

Australian Journal of Chemistry

Type

Journal article

DOI

10.1071/CH10198

Restricted until

2037-12-31

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