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Carbon-carbon and carbon-chlorine bond formation on reaction of iodine(III) reagents with the bis(alkynyl)palladium(II) motif, and structural chemistry of trans -Pd(C≡C- o -Tol) 2 (PMe 2 Ph) 2 ] and trans -[PdCl(C≡C- o -Tol) 2 (PMe 2 Ph) 2 ]

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dc.contributor.authorSharma, Manab
dc.contributor.authorCanty, Allan
dc.contributor.authorGardiner, Michael G
dc.contributor.authorJones, Roderick C.
dc.date.accessioned2015-12-10T23:01:51Z
dc.date.issued2011
dc.date.updated2016-02-24T10:44:37Z
dc.description.abstractTrans-di(ortho-tolylethynyl)bis(dimethylphenylphosphine)palladium(II) reacts above -20 °C with the iodonium reagent IPhCl2 to give predominantly o-Tol-CC-Cl, above 15 °C with IPh2(OTf) (OTf = triflate) to give o-Tol-CC-Ph and (o-Tol-CC)2 in ca. 3:1 rati
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/1885/61772
dc.publisherElsevier
dc.sourceJournal of Organometallic Chemistry
dc.subjectKeywords: Alkynylpalladium; Alkynyls; Bond formation; Carbon-carbon bond formation; Iodonium; NMR spectrum; Reductive elimination; Structural chemistry; Triflates; Chemical bonds; Chlorine; Iodine; Nuclear magnetic resonance spectroscopy; Oxidation; Palladium; X ra Alkynyl; Alkynylpalladium; Carbon-carbon bond formation; Oxidation; Palladium; Reductive elimination
dc.titleCarbon-carbon and carbon-chlorine bond formation on reaction of iodine(III) reagents with the bis(alkynyl)palladium(II) motif, and structural chemistry of trans -Pd(C≡C- o -Tol) 2 (PMe 2 Ph) 2 ] and trans -[PdCl(C≡C- o -Tol) 2 (PMe 2 Ph) 2 ]
dc.typeJournal article
local.bibliographicCitation.issue7
local.bibliographicCitation.lastpage1444
local.bibliographicCitation.startpage1441
local.contributor.affiliationSharma, Manab, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCanty, Allan, University of Tasmania
local.contributor.affiliationGardiner, Michael G, University of Tasmania
local.contributor.affiliationJones, Roderick C., University of Tasmania
local.contributor.authoruidSharma, Manab, u4939765
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationU4217927xPUB638
local.identifier.citationvolume696
local.identifier.doi10.1016/j.jorganchem.2011.01.018
local.identifier.scopusID2-s2.0-79952452885
local.identifier.thomsonID000289236800016
local.type.statusPublished Version

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