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A three dimensional hydrogen bonded organic framework assembled through antielectrostatic hydrogen bonds

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Date

2019

Authors

Cullen, Duncan
Gardiner, Michael
White, Nicholas

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

A crystalline 3D hydrogen bonded framework is assembled in water from tetrahedral tetraamidinium cations and antielectrostatically hydrogen bonded bicarbonate dimers. The framework forms in water, and represents a clear demonstration of the potency of these anti-Coulombic hydrogen bonds. Gentle heating of the framework (50 °C) releases CO2 and water to give the neutral tetraamidine compound.

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Citation

URI

http://hdl.handle.net/1885/209269

Collections

ANU Research Publications

Source

Chemical Communications

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/c9cc06707h

Restricted until

2037-12-31

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01_Cullen_A_three_dimensional_hydrogen_2019.pdf (2.19 MB)

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