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Metallocyclodextrin catalysts for hydrolysis of phosphate triesters

Date

Authors

Barr, Lorna

Easton, Christopher

Lee, Kitty

Lincoln, Stephen F

Simpson, Jamie S

Publisher

Elsevier

Abstract

The copper complexes of 6A-(2-aminoethylamino)- and 6A-(3-aminopropylamino)-6A-deoxy-β-cyclodextrin catalyse the hydrolysis of 4-tert-butyl-2-nitrophenyl dimethyl phosphate, with kinc=3.1×10-2 and 2.3×10-2 s-1, and Kd=4.3×10-4 and 1.2×10-3 M, respect

Keywords

Keywords: 4 tert butyl 2 nitrophenyldimethylphosphate; benzene derivative; beta cyclodextrin derivative; buffer; copper complex; cyclodextrin derivative; metallocyclodextrin; organophosphate; unclassified drug; article; catalyst; chemical binding; chemical reaction

URI

http://hdl.handle.net/1885/91700

Collections

ANU Research Publications

Source

Tetrahedron Letters

Type

Journal article

DOI

10.1016/S0040-4039(02)01757-4

Restricted until

2037-12-31

Downloads

File

Description

01_Barr_Metallocyclodextrin_catalysts_2002.pdf (84.85 KB)