Rheological Properties of High Melt Strength Poly(ethylene terephthalate) Formed by Reactive Extrusion
| dc.contributor.author | Forsythe, John S. | |
| dc.contributor.author | Cheal, K. | |
| dc.contributor.author | Nisbet, David | |
| dc.contributor.author | Gupta, R.K. | |
| dc.contributor.author | Lau, A. | |
| dc.contributor.author | Donovan, A.R. | |
| dc.contributor.author | O'Shea, M.S. | |
| dc.contributor.author | Moad, Graeme | |
| dc.date.accessioned | 2015-12-10T23:12:08Z | |
| dc.date.issued | 2006 | |
| dc.date.updated | 2015-12-10T09:27:09Z | |
| dc.description.abstract | A reactive extrusion process was developed improving the rheological properties of PET via the coaddition of a dianhydride and polyol. Specifically, the coaddition of pyromellitic dianhydride (PMDA) with pentaerythritol resulted in a gel-free polyester with superior melt strengths and viscosities compared to the addition of PMDA alone. The enhancement in rheological properties were dependent on the relative amounts of dianhydride and polyol with the resultant polyester structurally stable in the melt. These results are consistent with the formation of a hyperbranched polyester with long chain branches. | |
| dc.identifier.issn | 0021-8995 | |
| dc.identifier.uri | http://hdl.handle.net/1885/63981 | |
| dc.publisher | John Wiley & Sons Inc | |
| dc.source | Journal of Applied Polymer Science | |
| dc.subject | Keywords: Alcohols; Extrusion; Polyesters; Rheology; Viscosity; Chain extension; Pentaerythritol; Reactive extrusion; Polyethylene terephthalates; extrusion; polyester; polyethylene terephthalate; strength; viscosity Branching; Chain extension; Pentaerythritol; PET; PMDA; Poly(ethylene terephthalate); Reactive extrusion | |
| dc.title | Rheological Properties of High Melt Strength Poly(ethylene terephthalate) Formed by Reactive Extrusion | |
| dc.type | Journal article | |
| local.bibliographicCitation.lastpage | 3652 | |
| local.bibliographicCitation.startpage | 3646 | |
| local.contributor.affiliation | Forsythe, John S., Monash University | |
| local.contributor.affiliation | Cheal, K., CSIRO Molecular Science | |
| local.contributor.affiliation | Nisbet, David, College of Engineering and Computer Science, ANU | |
| local.contributor.affiliation | Gupta, R.K., RMIT University | |
| local.contributor.affiliation | Lau, A., CSIRO Molecular Science | |
| local.contributor.affiliation | Donovan, A.R., CSIRO Molecular Science | |
| local.contributor.affiliation | O'Shea, M.S., CSIRO Molecular Science | |
| local.contributor.affiliation | Moad, Graeme, CSIRO Molecular and Health Technologies | |
| local.contributor.authoruid | Nisbet, David, u5031428 | |
| local.description.embargo | 2037-12-31 | |
| local.description.notes | Imported from ARIES | |
| local.identifier.absfor | 090302 - Biomechanical Engineering | |
| local.identifier.absfor | 100708 - Nanomaterials | |
| local.identifier.absfor | 091202 - Composite and Hybrid Materials | |
| local.identifier.absseo | 970106 - Expanding Knowledge in the Biological Sciences | |
| local.identifier.absseo | 970111 - Expanding Knowledge in the Medical and Health Sciences | |
| local.identifier.absseo | 970109 - Expanding Knowledge in Engineering | |
| local.identifier.ariespublication | u4334215xPUB872 | |
| local.identifier.citationvolume | 100 | |
| local.identifier.doi | 10.1002/app.23166 | |
| local.identifier.scopusID | 2-s2.0-33646362260 | |
| local.type.status | Published Version |
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