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Rheological Properties of High Melt Strength Poly(ethylene terephthalate) Formed by Reactive Extrusion

dc.contributor.authorForsythe, John S.
dc.contributor.authorCheal, K.
dc.contributor.authorNisbet, David
dc.contributor.authorGupta, R.K.
dc.contributor.authorLau, A.
dc.contributor.authorDonovan, A.R.
dc.contributor.authorO'Shea, M.S.
dc.contributor.authorMoad, Graeme
dc.date.accessioned2015-12-10T23:12:08Z
dc.date.issued2006
dc.date.updated2015-12-10T09:27:09Z
dc.description.abstractA reactive extrusion process was developed improving the rheological properties of PET via the coaddition of a dianhydride and polyol. Specifically, the coaddition of pyromellitic dianhydride (PMDA) with pentaerythritol resulted in a gel-free polyester with superior melt strengths and viscosities compared to the addition of PMDA alone. The enhancement in rheological properties were dependent on the relative amounts of dianhydride and polyol with the resultant polyester structurally stable in the melt. These results are consistent with the formation of a hyperbranched polyester with long chain branches.
dc.identifier.issn0021-8995
dc.identifier.urihttp://hdl.handle.net/1885/63981
dc.publisherJohn Wiley & Sons Inc
dc.sourceJournal of Applied Polymer Science
dc.subjectKeywords: Alcohols; Extrusion; Polyesters; Rheology; Viscosity; Chain extension; Pentaerythritol; Reactive extrusion; Polyethylene terephthalates; extrusion; polyester; polyethylene terephthalate; strength; viscosity Branching; Chain extension; Pentaerythritol; PET; PMDA; Poly(ethylene terephthalate); Reactive extrusion
dc.titleRheological Properties of High Melt Strength Poly(ethylene terephthalate) Formed by Reactive Extrusion
dc.typeJournal article
local.bibliographicCitation.lastpage3652
local.bibliographicCitation.startpage3646
local.contributor.affiliationForsythe, John S., Monash University
local.contributor.affiliationCheal, K., CSIRO Molecular Science
local.contributor.affiliationNisbet, David, College of Engineering and Computer Science, ANU
local.contributor.affiliationGupta, R.K., RMIT University
local.contributor.affiliationLau, A., CSIRO Molecular Science
local.contributor.affiliationDonovan, A.R., CSIRO Molecular Science
local.contributor.affiliationO'Shea, M.S., CSIRO Molecular Science
local.contributor.affiliationMoad, Graeme, CSIRO Molecular and Health Technologies
local.contributor.authoruidNisbet, David, u5031428
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor090302 - Biomechanical Engineering
local.identifier.absfor100708 - Nanomaterials
local.identifier.absfor091202 - Composite and Hybrid Materials
local.identifier.absseo970106 - Expanding Knowledge in the Biological Sciences
local.identifier.absseo970111 - Expanding Knowledge in the Medical and Health Sciences
local.identifier.absseo970109 - Expanding Knowledge in Engineering
local.identifier.ariespublicationu4334215xPUB872
local.identifier.citationvolume100
local.identifier.doi10.1002/app.23166
local.identifier.scopusID2-s2.0-33646362260
local.type.statusPublished Version

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