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Crystal Structure of Cs 2 Zn(NO 2 ) 4 : Influence of Steric Crowding on Nitrite Coordination

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Date

2005

Authors

Oates, Susan
Hitchman, Michael
Skelton, Brian
Stranger, Robert
Stratemeier, Horst
White, Allan

Journal Title

Journal ISSN

Volume Title

Publisher

CSIRO Publishing

Abstract

The crystal structure of Cs2[Zn(NO2)4] has been determined by X-ray diffraction. Each nitrite ion in the Zn(NO 2)42- group forms one short [2.080(3) Å] and one long [2.516(3) A] Zn-O bond, the metal-ligand interaction being intermediate between symmetric

Description

Keywords

Keywords: Chelation; Crystal structure; Evaporation; Filtration; Potential energy; Precipitation (chemical); Probability density function; Solutions; X ray diffraction analysis; Metal ions; Metal-ligand interaction; Nitrite chelates; Zinc nitrite; Cesium compounds

Citation

URI

http://hdl.handle.net/1885/83945

Collections

ANU Research Publications

Source

Australian Journal of Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1071/CH04270

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