Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

A ferrocene redox-active triazolium macrocycle that binds and senses chloride

Simple item page
dc.contributor.authorWhite, Nicholas
dc.contributor.authorBeer, Paul D.
dc.date.accessioned2018-11-29T22:56:02Z
dc.date.available2018-11-29T22:56:02Z
dc.date.issued2012
dc.date.updated2018-11-29T08:09:41Z
dc.description.abstractA ferrocene bis(triazole) macrocycle was synthesised in good yield by the Eglinton coupling of an acyclic bis(alkyne) precursor and characterised in the solid state by X-ray crystallography. Alkylation gives the corresponding triazolium macrocycle, which binds chloride and benzoate strongly in CD3CN solution through favourable charge-assisted C–H···anion interactions, as evidenced by 1H NMR titration experiments. Preliminary electrochemical studies reveal that the redox-active macrocycle is capable of sensing chloride in CH3CN solution.
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn1860-5397
dc.identifier.urihttp://hdl.handle.net/1885/153379
dc.publisherBeilstein-Institut
dc.sourceBeilstein Journal of Organic Chemistry
dc.subjectKeywords: Anion binding; C-H···anion interactions; Electrochemistry; Ferrocene; Triazolium
dc.titleA ferrocene redox-active triazolium macrocycle that binds and senses chloride
dc.typeJournal article
dcterms.accessRightsOpen Accessen_AU
local.bibliographicCitation.lastpage252
local.bibliographicCitation.startpage246
local.contributor.affiliationWhite, Nicholas, College of Science, ANU
local.contributor.affiliationBeer, Paul D., University of Oxford
local.contributor.authoruidWhite, Nicholas, u1011016
local.description.notesImported from ARIES
local.identifier.absfor030302 - Nanochemistry and Supramolecular Chemistry
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationu8801298xPUB159
local.identifier.citationvolume8
local.identifier.doi10.3762/bjoc.8.25
local.identifier.scopusID2-s2.0-84856864845
local.identifier.thomsonID000300108600001
local.type.statusPublished Version

Downloads

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
01_White_A_ferrocene_redox-active_2012.pdf
Size:
778.9 KB
Format:
Adobe Portable Document Format
Download

Collections

ANU Research Publications

DSpace software copyright © 2002-2026 LYRASIS