Bimetallic Dihydrobis(methimazolyl)borate Coordination: Molecular Structure [Mo 2 Au{μ 2 -H 2 B(mt) 2 }(PPh 3 )(CO) 7 ] (mt = methimazolyl)

Cade, Ian; Hill, Anthony; Tshabang, Never; Smith, Matthew

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Bimetallic Dihydrobis(methimazolyl)borate Coordination: Molecular Structure [Mo 2 Au{μ 2 -H 2 B(mt) 2 }(PPh 3 )(CO) 7 ] (mt = methimazolyl)

Date

2009

Authors

Cade, Ian

Hill, Anthony

Tshabang, Never

Smith, Matthew

Publisher

American Chemical Society

Abstract

The sequential treatment ofNa[H2B(mt)2] (mt = methimazolyl) with [Mo(pip)2(CO)4] (pip = piperidine), [Mo(CO)3(L)3] (L = NCMe, L3 = η6-C7H8) and [AuCl(PPh3)] provides the diheterotrimetallie complex [Mo2Au{μ-H 2B(mt)2}(CO)7PPh3)] in which each thione gro