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Should dithiophosphinate esters function as RAFT agents?

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Authors

Hodgson, Jennifer
Green, Katy
Coote, Michelle

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American Chemical Society

Abstract

(Chemical Equation Presented) High-level ab initio calculations indicate that•CH3 addition to the sulfur center of S=P(Z)(Z′)SCH3 (Z,Z′ = CH3, CN, OCH3, Ph) is considerably less exothermic than addition to the corresponding RAFT agents, S=C(Z)SCH3.

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Organic Letters

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Restricted until

2037-12-31