Should dithiophosphinate esters function as RAFT agents?
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Hodgson, Jennifer
Green, Katy
Coote, Michelle
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American Chemical Society
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(Chemical Equation Presented) High-level ab initio calculations indicate that•CH3 addition to the sulfur center of S=P(Z)(Z′)SCH3 (Z,Z′ = CH3, CN, OCH3, Ph) is considerably less exothermic than addition to the corresponding RAFT agents, S=C(Z)SCH3.
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Organic Letters
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2037-12-31
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