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Tetrel and pnictogen functionalised propargylidynes

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dc.contributor.authorManzano, Richard
dc.contributor.authorHill, Anthony
dc.contributor.authorGeorgelin, Rosemary
dc.date.accessioned2020-12-13T22:57:37Z
dc.date.issued2020-12-04
dc.description.abstractThe reaction of [W([triple bond, length as m-dash]CC[triple bond, length as m-dash]CSiMe3)(CO)2(Tp*)] (Tp* = tris(dimethylpyrazolyl)borate) with AgNO3 affords {[W([triple bond, length as m-dash]CC[triple bond, length as m-dash]CAg)-(CO)2(Tp*)][AgNO3]}n while [Hg{C[triple bond, length as m-dash]CC[triple bond, length as m-dash]W(CO)2(Tp*)}2] with nBuLi affords [W([triple bond, length as m-dash]CC[triple bond, length as m-dash]CLi)(CO)2(Tp*)]. These anhydrous reagents allow the installation of main group elements (e.g., Si, Sn, Pb, P, As) as propargylidyne termini.en_AU
dc.description.sponsorshipDP170102695 and DP190100723en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn1359-7345en_AU
dc.identifier.urihttp://hdl.handle.net/1885/216915
dc.language.isoen_AUen_AU
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/18003..."The Accepted Version can be archived in a Non-Commercial Repository. 12 months embargo" from SHERPA/RoMEO site (as at 13/12/2020).en_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP170102695en_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP190100723en_AU
dc.rights© Royal Society of Chemistry 2020en_AU
dc.sourceChemical communicationsen_AU
dc.titleTetrel and pnictogen functionalised propargylidynesen_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Accessen_AU
local.bibliographicCitation.issue93en_AU
local.bibliographicCitation.lastpage14600en_AU
local.bibliographicCitation.startpage14597en_AU
local.contributor.affiliationManzano, R., Research Schoolof Chemistry, The Australian National Universityen_AU
local.contributor.affiliationHill, A., Research School of Chemistry, The Australian National Universityen_AU
local.contributor.affiliationGeorgelin, R. L., Research School of Chemistry, The Australian National Universityen_AU
local.contributor.authoruidu4030185en_AU
local.identifier.citationvolume56en_AU
local.identifier.doi10.1039/d0cc06196den_AU
local.identifier.essn1364-548Xen_AU
local.publisher.urlhttp://pubs.rsc.org/en/Journals/JournalIssues/CCen_AU
local.type.statusAccepted Versionen_AU

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