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A synthetic approach to a novel class of fluorine-bearing reversible addition-fragmentation chain transfer(RAFT) agents: F-RAFT

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dc.contributor.authorTheis, Alexander
dc.contributor.authorStenzel, Martina H
dc.contributor.authorDavis, Thomas P
dc.contributor.authorCoote, Michelle
dc.contributor.authorBarner-Kowollik, Christopher
dc.date.accessioned2015-12-13T22:53:09Z
dc.date.issued2005
dc.date.updated2015-12-11T10:54:45Z
dc.description.abstractA synthetic route is described to a novel class of reversible addition-fragmentation chain transfer (RAFT) agents bearing a fluorine Z-group. Such F-RAFT agents are theoretically predicted to allow living free radical polymerization of various monomers without affecting the rate of polymerization, and should also facilitate the construction of block copolymers from monomers with disparate reactivity. The class of F-RAFT agents is exemplified by the example of benzyl fluoro dithioformate (BFDF) in styrene free-radical polymerizations and the process is shown to induce living polymerization.
dc.identifier.issn0004-9425
dc.identifier.urihttp://hdl.handle.net/1885/81687
dc.publisherCSIRO Publishing
dc.sourceAustralian Journal of Chemistry
dc.subjectKeywords: Benzene; Copolymers; Fluorine; Free radicals; Monomers; Polyvinyl acetates; Styrene; Benzyl fluoro dithioformate (BFDF); Free-radical polymerizations; Reversible addition and fragmentation chain transfer (RAFT); Living polymerization
dc.titleA synthetic approach to a novel class of fluorine-bearing reversible addition-fragmentation chain transfer(RAFT) agents: F-RAFT
dc.typeJournal article
local.bibliographicCitation.issue6
local.bibliographicCitation.lastpage441
local.bibliographicCitation.startpage437
local.contributor.affiliationTheis, Alexander, University of New South Wales
local.contributor.affiliationStenzel, Martina H, University of New South Wales
local.contributor.affiliationDavis, Thomas P, University of New South Wales
local.contributor.affiliationCoote, Michelle, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationBarner-Kowollik, Christopher, University of New South Wales
local.contributor.authoruidCoote, Michelle, u4031074
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030305 - Polymerisation Mechanisms
local.identifier.absfor030799 - Theoretical and Computational Chemistry not elsewhere classified
local.identifier.ariespublicationMigratedxPub9988
local.identifier.citationvolume58
local.identifier.doi10.1071/CH05069
local.identifier.scopusID2-s2.0-22744452040
local.type.statusPublished Version

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