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Evidence from FTIR Difference Spectroscopy of an Extensive Network of Hydrogen Bonds near the Oxygen-Evolving Mn4Ca Cluster of Photosystem II Involving D1-Glu65, D2-Glu312, and D1-Glu329

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Date

2010

Authors

Service, Rachel J
Hillier, Warwick
Debus, Richard John

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

Analyses of the refined X-ray crystallographic structures of photosystem II (PSII) at 2.9-3.5 Å have revealed the presence of possible channels for the removal of protons from the catalytic Mn4Ca cluster during the water-splitting reaction. As an initial

Description

Keywords

Keywords: [carbonyl; Carboxylate groups; Common networks; Crystallographic models; Cyanobacterium synechocystis; Electrostatic interactions; Extended networks; FTIR; FTIR difference spectroscopy; Photosystem II; Positive charges; Protonated; Protonation state; PSII

Citation

URI

http://hdl.handle.net/1885/31057

Collections

ANU Research Publications

Source

Biochemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/bi100730d

Restricted until

2037-12-31

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Description
01_Service_Evidence_from_FTIR_Difference_2010.pdf (4.6 MB)

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