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Enhanced stereocontrol in Diels-Alder reactions of chiral dienols

Date

Authors

Cayzer, Tory

Miller, Natalie

Paddon-Row, Michael

Sherburn, Michael

Publisher

Royal Society of Chemistry

Abstract

This combined experimental-computational investigation demonstrates that the presence of a removable bromine substituent on a diene leads to complete π-diastereofacial and endo/exo stereoselection in both intermolecular and intramolecular Diels-Alder rea

Keywords

Keywords: Bromine; Chemical reactions; Isomers; Olefins; Stereochemistry; Synthesis (chemical); Bromine-containing analogue; Diels-Alder reactions; Diene; Aromatic compounds; Betulaceae

URI

http://hdl.handle.net/1885/83531

Collections

ANU Research Publications

Source

Organic and Biomolecular Chemistry

Type

Journal article

DOI

10.1039/b602618d

Restricted until

2037-12-31

Downloads

File

Description

01_Cayzer_Enhanced_stereocontrol_in_2006.pdf (281.17 KB)