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Ammonium-crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster-metal coordination polymer with enhanced NLO properties **

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Date

2016

Authors

Zhang, Jinfang
Jia, Ding
Meng, Suci
Zaworotko, Michael J.
Cifuentes, Marie
Zhang, Chi
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

An ammonium–crown ether host–guest supramolecular cation-templated synthetic methodology has been developed to construct a structurally unprecedented heterobicluster–metal coordination polymer (HCM-CP 1) based on tetranuclear clusters [WS4Cu3]+ with different connection environments, pentanuclear clusters [WS4Cu4]2+, and Cu+ building metal ions. HCM-CP 1 exhibits enhanced NLO properties, which may be ascribed to the incorporation of diverse building cluster components

Description

Keywords

Citation

URI

http://hdl.handle.net/1885/102935

Collections

ANU Research Publications

Source

Chemical Communications

Type

Journal article

Book Title

Entity type

Access Statement

Open Access

License Rights

DOI

10.1039/c5cc10076c

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MGH284-preprint-1.pdf (619.69 KB)

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