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Fast and catalyst-free hetero-Diels-Alder chemistry for on demand cyclable bonding/debonding materials

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Date

2013

Authors

Oehlenschlaeger, Kim
Guimard, Nathalie
Brandt, Josef
Mueller, Jan O.
Lin, Ching-Yeh
Hilf, Stefan
Lederer, Albena
Coote, Michelle
Schmidt, Friedrich Georg
Barner-Kowollik, Christopher

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

A new dithioester possessing a cyano Z-group (cyano-dithioester (CDTE)) has been synthesized via a 2-step, one-pot reaction. The cyano-substituted dithioester has been found to undergo fast reversible hetero-Diels-Alder (HDA) reactions at ambient temperat

Description

Keywords

Keywords: Ab initio molecular orbital calculation; Hetero-diels-Alder; On-demand systems; On-line NMR spectroscopy; One-pot reaction; Polymerization reaction; Reversible bonding; UV-vis spectroscopy; Calculations; Catalysts; Directive antennas; Experiments; Nuclear

Citation

URI

http://hdl.handle.net/1885/73382

Collections

ANU Research Publications

Source

Polymer Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/c3py00476g

Restricted until

2037-12-31

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01_Oehlenschlaeger_Fast_and_catalyst-free_2013.pdf (717.78 KB)

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