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The Synthesis, Structural Characterisation and Chemical Manipulation of the [6+3] Cycloadduct Derived from alpha-Tropolone O-Methyl Ether and Trimethylenemethane

Date

2019

Authors

Crisp, Antony
Noble, Dr Benjamin
Schwartz, Brett
Willis, Anthony
Coote, Michelle
Banwell, Martin

Journal Title

Journal ISSN

Volume Title

Publisher

Wiley

Abstract

The title bicyclic system 3, the adduct arising from the formal [6+3] cycloaddition of α‐tropolone O‐methyl ether (1) and trimethylenemethane (2), has been prepared and subject to single‐crystal X‐ray analysis. The chemical manipulation of adduct 3 in a range of ways is reported, including through acid‐catalysed rearrangement of the derived mono‐oxide to give the bicyclo[4.3.1]undecane 21.

Description

Keywords

Citation

Source

Asian Journal of Organic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

Open Access

License Rights

DOI

10.1002/ajoc.201900334

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