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Enhanced two-photon absorption cross-sections of zinc(II) tetraphenylporphyrins peripherally substituted with d 6 -metal alkynyl complexes

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Authors

Drouet, Samuel
Merhi, Areej
Grelaud, Guillaume
Cifuentes, Marie
Matczyszyn, Katarzyna
Samoc, Marek
Toupet, L
Paul-Roth, Christine
Paul, Frederic
Humphrey, Mark

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Royal Society of Chemistry

Abstract

The syntheses of new Zn(ii) tetraphenylporphyrin (ZnTPP) derivatives functionalized with electron-rich d6-transition metal alkynyl complexes at their periphery are reported. Z-scan measurements reveal remarkably large effective two-photon absorption (TPA) cross-sections in the visible range for these compounds. This journal is

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New Journal of Chemistry

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2037-12-31