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Syntheses of the D-aldopentoses from non-carbohydrate sources

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Date

1999

Authors

Banwell, Martin
De Savi, Chris
Hockless, David
Pallich, Susanne
Watson, Keith G

Journal Title

Journal ISSN

Volume Title

Publisher

Georg Thieme Verlag

Abstract

The cis-1,2-dihydrocatechols 5-7, which are obtained in high yield and ca. 99.8% ee by microbial oxidation of the corresponding aromatic compound, have been converted, via reaction sequences involving three distinct types of one-carbon deletion processes, into the four D-aldopentoses.

Description

Keywords

Keywords: pentose; article; carbohydrate analysis; carbohydrate metabolism; carbohydrate synthesis; chemical analysis; oxidation 1,2-diol cleavage; Cis-1,2-dihydrocatechol; D- xylose; D-arabinose; D-lyxono-d- lactone; D-lyxose; D-ribose; Ozonolytic cleavage; Radical decarboxylation

Citation

URI

http://hdl.handle.net/1885/93741

Collections

ANU Research Publications

Source

Synlett

Type

Journal article

Book Title

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