Synthesis, characterization, and electrochemical relationships of dinuclear complexes of platinum(II) and platinum(III) containing ortho-metalated tertiary arsine ligands

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Bennett, Martin
Bhargava, Suresh Kumar
Bond, I A
Edwards, Alison
Guo, Si-Xuan
Priver, Steven H
Rae, A David
Willis, Anthony

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American Chemical Society

Abstract

Reaction of 2-Li-4-MeC6H3AsPh2 with [PtCl2(SEt2)2] gives two isomeric dinuclear platinum(II) complexes, one containing a half-lantern structure with two chelating and two bridging C6H3-5-Me-2-AsPh2 ligands, [Pt2(κ2As,C-C6H 3-5-Me-2-AsPh2)2(μ-κAs,κC-C

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Inorganic Chemistry

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Restricted until

2037-12-31