Recent advances in light-regulated non-radical polymerisations

dc.contributor.authorLai, Haiwang
dc.contributor.authorZhang, Jing
dc.contributor.authorXing, Feiyue
dc.contributor.authorXiao, Pu
dc.date.accessioned2022-09-19T05:26:57Z
dc.date.issued2020
dc.date.updated2024-03-03T07:15:46Z
dc.description.abstractLight is one of the non-invasive stimuli which can be used in the spatiotemporal control of chemical reactions. Over the past decade, light has found wide applications in polymer science such as polymer synthesis, release of small molecules from polymers and polymeric photosensors etc. Reviews on light-regulated polymerisations have predominately focused on the free radical process. However, the marriage of light to non-radical polymerisations, e.g. ionic, ring-opening, metathesis, step-growth and supramolecular photopolymerisations, has also spurred tremendous research interest to develop materials. These kinds of non-radical photopolymerisations, compared to the free radical approach, are advantageous in overcoming oxygen inhibition, accessing novel polymer structures and fabricating degradable and dynamic polymers. The relevant light-regulation techniques involved in these polymerisations are usually based on photolinking reactions and photoactivation of latent species. These species produce initiators, catalysts or monomers upon light irradiation to manipulate polymer formation. These techniques have been successfully implemented to adapt conditional polymerisations under light, discover novel polymerisation methods and precisely control polymer structures. This review aims to highlight the recent progress in light-regulated non-radical polymerisations in the development of polymerisation techniques as well as the applications in materials science, emphasising the remaining challenges and promising perspective in the relevant fields.
dc.description.sponsorshipHL acknowledges China Postdoctoral Science Foundation Grant (2019TQ0119)en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn0306-0012en_AU
dc.identifier.urihttp://hdl.handle.net/1885/272894
dc.language.isoen_AUen_AU
dc.publisherRoyal Society of Chemistry
dc.relationhttp://purl.org/au-research/grants/arc/FT170100301
dc.rights© 2020 The authors
dc.sourceChemical Society Reviews
dc.titleRecent advances in light-regulated non-radical polymerisations
dc.typeJournal article
local.bibliographicCitation.issue6en_AU
local.bibliographicCitation.lastpage1886en_AU
local.bibliographicCitation.startpage1867en_AU
local.contributor.affiliationLai, Haiwang, College of Science, ANUen_AU
local.contributor.affiliationZhang, Jing, College of Science, ANUen_AU
local.contributor.affiliationXing, Feiyue, Jinan Universityen_AU
local.contributor.affiliationXiao, Pu, College of Science, ANUen_AU
local.contributor.authoremailu1066289@anu.edu.auen_AU
local.contributor.authoruidLai, Haiwang, u1066289en_AU
local.contributor.authoruidZhang, Jing, u4066306en_AU
local.contributor.authoruidXiao, Pu, u1053596en_AU
local.description.embargo2099-12-31
local.description.notesImported from ARIESen_AU
local.identifier.absfor000000 - Internal ANU use onlyen_AU
local.identifier.ariespublicationa383154xPUB11204en_AU
local.identifier.citationvolume49en_AU
local.identifier.doi10.1039/c9cs00731hen_AU
local.identifier.thomsonIDWOS:000524557800007
local.identifier.uidSubmittedBya383154en_AU
local.publisher.urlhttps://pubs.rsc.org/en_AU
local.type.statusPublished Versionen_AU

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