Mixed-metal cluster chemistry. 24. Isocyanide derivatives of [MoIr 3 (μ-CO) 3 (CO) 8 (η-C 5 H 5 )] and [Mo 2 Ir 2 (μ-CO) 3 (CO) 7 (η-C 5 H 5 ) 2
Date
2003
Authors
Usher, Alistair
Willis, Anthony
Humphrey, Mark
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Elsevier
Abstract
Reactions of MoIr3(μ-CO)3(CO)8 (η-C5H5) (1) with stoichiometric amounts of isocyanides afford the ligand-substituted clusters [MoIr3(μ-CO)3(CO)8-n(L)n (η-C5H5)] (L=CNBut, n=1 (3), 2 (4), 3 (5); L=CNC6H3Me2-2,6, n=1 (6), 2 (7), 3 (8)) in moderate to ex
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Keywords
Keywords: carbonyl derivative; coordination compound; cyanide; iridium complex; ligand; molybdenum complex; article; chemical reaction; cluster analysis; controlled study; crystal structure; stoichiometry; X ray analysis Carbonyl; Cluster; Cyclopentadienyl; Iridium; Isocyanide; Molybdenum
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Journal of Organometallic Chemistry
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Journal article
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