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A unique mechanism for base catalyzed hydrolysis of pentaaminecobalt(III) complexes containing picolyl residues

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Date

2003

Authors

Dickie, Alistair J
Hockless, David
Willis, Anthony
McKeon, Josephine A
Jackson, William Gregory

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

A novel [Co(pentaamine)CI]2+ complex having all tertiary amine or pyridine donors has been synthesized (pentaamine = 1,4-bis(2′-pyridyl)-7-methyl-1,4,7-triazacyclononane). This asym-[Co(dmpmetacn)Cl]2+ species has been completely characterized through 1

Description

Keywords

Keywords: amine; base; carbene; cobalt [1,4 bis(2' pyridyl) 7 methyl 1,4,7 triazacyclononane]; cobalt complex; unclassified drug; amination; article; catalysis; catalyst; chemical structure; hydrolysis; nuclear magnetic resonance; proton transport; reaction analysi

Citation

URI

http://hdl.handle.net/1885/87668

Collections

ANU Research Publications

Source

Inorganic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/ic0206995

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