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Heterobimetallic C 3 complexes through silylpropargylidyne desilylation

Date

Authors

Dewhurst, Rian

Hill, Anthony

Smith, Matthew

Publisher

Wiley-VCH Verlag GMBH

Abstract

Odd compounds: The study of bimetallic complexes spanned by linear carbon chains was mainly restricted to even-numbered chains. The fluorodesilylation of silylated propargylidynes now provides a range of C3-spanned heterobimetallic complexes based on Ru and either Mo or W (e.g. see picture).

Keywords

Keywords: Carbon; Molybdenum; Organic compounds; Ruthenium; Tungsten; Desilylation; Linear carbon chains; Bimetals; metal complex; silylpropargylidene; unclassified drug; article; chemical analysis; chemical reaction; complex formation; crystallography; geometry; n Alkynes; Carbynes; Multiple bonds; Ruthenium; Tungsten

URI

http://hdl.handle.net/1885/78081

Collections

ANU Research Publications

Source

Angewandte Chemie International Edition

Type

Journal article

DOI

10.1002/anie.200352693

Restricted until

2037-12-31

Downloads

File

Description

01_Dewhurst_Heterobimetallic_C_3__2004.pdf (144.96 KB)

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