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New protocols for the assembly of the tetracyclic framework associated with the aromatic erythrina alkaloids

Date

Authors

Stanislawski, Pauline

Willis, Anthony

Banwell, Martin

Publisher

American Chemical Society

Abstract

Treatment of the anion derived from the ring-fused gem-dichlorocyclopropane 4c with silver tetrafluoroborate afforded the spirocyclic compound 17 in 74% yield. Product 17 was readily converted, over three steps, into the β-odoethyl derivative 20 and trea

Keywords

Keywords: alkaloid; article; chemical structure; chemistry; cyclization; Erythrina; isolation and purification; medicinal plant; synthesis; Alkaloids; Cyclization; Erythrina; Molecular Structure; Plants, Medicinal

URI

http://hdl.handle.net/1885/85235

Collections

ANU Research Publications

Source

Organic Letters

Type

Journal article

DOI

10.1021/ol060642c

Restricted until

2037-12-31

Downloads

File

Description

01_Stanislawski_New_protocols_for_the_assembly_2006.pdf (74.91 KB)

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