Facile reduction of coordinated α-imino acids to amino acids by dithionite and borohydride.

Pearce, Dierdre; Hartshorn, Richard; Sargeson, Alan

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Facile reduction of coordinated α-imino acids to amino acids by dithionite and borohydride.

Date

2002

Authors

Pearce, Dierdre

Hartshorn, Richard

Sargeson, Alan

Publisher

Royal Society of Chemistry

Abstract

Sodium dithionite was found to reduce a range of α-iminoacidato ligands, chelated to cobalt(III), to the related α-aminoacidato species. For the bis(1,2-ethanediamine) system, the distribution of the products showed a small stereoselectivity towards the

Keywords

Keywords: Chelation; Molecules; pH effects; Reduction; Imino acids; Amino acids

URI

http://hdl.handle.net/1885/72565

Collections

ANU Research Publications

Source

Dalton Transactions

Type

Journal article

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Facile reduction of coordinated α-imino acids to amino acids by dithionite and borohydride.

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