Electron-rich iron/ruthenium arylalkynyl complexes for third-order nonlinear optics: redox-switching between three states
Date
2011
Authors
Gauthier, Nicolas
Argouarch, Gilles
Paul, Frederic
Toupet, L
Ladjarafi, A.
Costuas, Karine
Halet, Jean-Francois
Samoc, Marek
Cifuentes, Marie
Corkery, Timothy
Journal Title
Journal ISSN
Volume Title
Publisher
Wiley-VCH Verlag GMBH
Abstract
The new [(n2-dppe)(n5-C5Me5)Fe(CξC-1,4-C6H4CξC)Ru(n2-dppe)2CξC(C6H5)] complex (3-H) and its hexanuclear relative [{(n2-dppe)(n5-C5Me5)Fe(CξC-1,4-C6H4-CξC) Ru(n2-dppe)2(CξC-1,4-C6H4CξC)3(1,3,5-C6H3)] (4) have been synthesized and characterized. The
Description
Keywords
Keywords: Analogous complexes; Biradical structures; Carbon rich; Density-functional calculations; Dinuclear; Electron-rich; Experimental evidence; Heterometallic complexes; Heteronuclear; Intervalence charge-transfer; Mixed-valent; Near-infrared range; Non-linear density functional calculations; heterometallic complexes; nonlinear optics; organometallic compounds; redox switching
Citation
Collections
Source
Chemistry, A European Journal
Type
Journal article
Book Title
Entity type
Access Statement
License Rights
Restricted until
2037-12-31