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Electron-rich iron/ruthenium arylalkynyl complexes for third-order nonlinear optics: redox-switching between three states

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Date

2011

Authors

Gauthier, Nicolas
Argouarch, Gilles
Paul, Frederic
Toupet, L
Ladjarafi, A.
Costuas, Karine
Halet, Jean-Francois
Samoc, Marek
Cifuentes, Marie
Corkery, Timothy

Journal Title

Journal ISSN

Volume Title

Publisher

Wiley-VCH Verlag GMBH

Abstract

The new [(n2-dppe)(n5-C5Me5)Fe(CξC-1,4-C6H4CξC)Ru(n2-dppe)2CξC(C6H5)] complex (3-H) and its hexanuclear relative [{(n2-dppe)(n5-C5Me5)Fe(CξC-1,4-C6H4-CξC) Ru(n2-dppe)2(CξC-1,4-C6H4CξC)3(1,3,5-C6H3)] (4) have been synthesized and characterized. The

Description

Keywords

Keywords: Analogous complexes; Biradical structures; Carbon rich; Density-functional calculations; Dinuclear; Electron-rich; Experimental evidence; Heterometallic complexes; Heteronuclear; Intervalence charge-transfer; Mixed-valent; Near-infrared range; Non-linear density functional calculations; heterometallic complexes; nonlinear optics; organometallic compounds; redox switching

Citation

URI

http://hdl.handle.net/1885/51290

Collections

ANU Research Publications

Source

Chemistry, A European Journal

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1002/chem.201003427

Restricted until

2037-12-31

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01_Gauthier_Electron-rich_iron/ruthenium_2011.pdf (993.88 KB)

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