Electron-rich iron/ruthenium arylalkynyl complexes for third-order nonlinear optics: redox-switching between three states

Gauthier, Nicolas; Argouarch, Gilles; Paul, Frederic; Toupet, L; Ladjarafi, A.; Costuas, Karine; Halet, Jean-Francois; Samoc, Marek; Cifuentes, Marie; Corkery, Timothy; Humphrey, Mark

Electron-rich iron/ruthenium arylalkynyl complexes for third-order nonlinear optics: redox-switching between three states

Date

2011

Authors

Gauthier, Nicolas

Argouarch, Gilles

Paul, Frederic

Toupet, L

Ladjarafi, A.

Costuas, Karine

Halet, Jean-Francois

Samoc, Marek

Cifuentes, Marie

Corkery, Timothy

Publisher

Wiley-VCH Verlag GMBH

Abstract

The new [(n2-dppe)(n5-C5Me5)Fe(CξC-1,4-C6H4CξC)Ru(n2-dppe)2CξC(C6H5)] complex (3-H) and its hexanuclear relative [{(n2-dppe)(n5-C5Me5)Fe(CξC-1,4-C6H4-CξC) Ru(n2-dppe)2(CξC-1,4-C6H4CξC)3(1,3,5-C6H3)] (4) have been synthesized and characterized. The