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Electrochemical Switching of the Cubic Nonlinear Optical Properties of an Aryldiethynyl-Linked Heterobimetallic Complex between Three Distinct States

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Date

2006

Authors

Samoc, Marek
Gauthier, Nicolas
Paul, Frederic
Lapinte, Claude
Cifuentes, Marie
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

Wiley-VCH Verlag GMBH

Abstract

(Chemical Equation Presented) Successive oxidation processes in a heterobimetallic iron-ruthenium complex (see picture) "switch" the optical transitions at long wavelengths, and these linear electrochromic effects are accompanied by changes in the nonlinear optical properties of the complex.

Description

Keywords

Keywords: Electrochemistry; Nonlinear optics; Optical properties; Optical switches; Alkynyl ligands; Heterobimetallic complex; Molecular switches; Metallic compounds Alkynyl ligands; Electrochemistry; Molecular switches; Nonlinear optics

Citation

URI

http://hdl.handle.net/1885/19591

Collections

ANU Research Publications

Source

Angewandte Chemie International Edition

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1002/anie.200602684

Restricted until

2037-12-31

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01_Samoc_Electrochemical_Switching_of_2006.pdf (132.82 KB)

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