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The role of Zn-OR and Zn-OH nucleophiles and the influence of para-substituents in the reactions of binuclear phosphatase mimetics

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Date

2012

Authors

Daumann, Lena J
Dalle, Kristian E
Schenk, Gerhard
McGeary, Ross Peter
Bernhardt, Paul
Ollis, David
Gahan, Lawrence

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

Analogues of the ligand 2,2′-(2-hydroxy-5-methyl-1,3-phenylene) bis(methylene)bis((pyridin-2-ylmethyl)azanediyl)diethanol (CH3H3L1) are described. Complexation of these analogues, 2,6-bis(((2-methoxyethyl)(pyridin-2-ylmethyl)amino)methyl)-4-methylphenol

Description

Keywords

Keywords: Bis(2 ,4-dinitrophenyl) phosphate; Electron-donating; Hydrolysis reaction; Mimetics; Nitrophenols; Solvent mixtures; Zinc complex; Complexation; Ethers; Hydrolysis; Ligands; Mass spectrometry; Nitrogen oxides; Nuclear magnetic resonance spectroscopy; Nucl

Citation

URI

http://hdl.handle.net/1885/60770

Collections

ANU Research Publications

Source

Dalton Transactions

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/c1dt11187f

Restricted until

2037-12-31

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01_Daumann_The_role_of_Zn-OR_and_Zn-OH_2012.pdf (410.79 KB)

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