Synthesis and coordination chemistry of new tetradentate N 2 S 2  donor Schiff-base ligand ca 2 -dapte: Mononuclear and dinuclear copper(I) complexes [Cu(ca 2 dapte)]ClO4 and [{Cu(PPh 3 )(X)} 2 (ca 2 dapte)] (X=I and Br)

Morshedi, Mahbod; Amirnasr, Mehdi; Slawin, Alexandra M. Z.; Woollins, J Derek; Khalaji, Aliakbar Dehno

Synthesis and coordination chemistry of new tetradentate N 2 S 2 donor Schiff-base ligand ca 2 -dapte: Mononuclear and dinuclear copper(I) complexes [Cu(ca 2 dapte)]ClO4 and [{Cu(PPh 3 )(X)} 2 (ca 2 dapte)] (X=I and Br)

Date

2009

Authors

Morshedi, Mahbod

Amirnasr, Mehdi

Slawin, Alexandra M. Z.

Woollins, J Derek

Khalaji, Aliakbar Dehno

Publisher

Pergamon-Elsevier Ltd

Abstract

A mononuclear copper(I) complex, [Cu(ca2dapte)]ClO4 (1), and two dinuclear copper(I) complexes, [{Cu(PPh3)(X)}2(ca2dapte)] (X = I (2) and Br (3)), of a new tetradentate N2S2 donor Schiff-base ligand ca2dapte have been prepared (ca2dapte = N,N′-bis(trans