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Synthesis of a thiocarbamoyl alkylidyne complex and caveats associated with the use of [Mo(≡CLi)(CO) 2 (Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate)

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dc.contributor.authorColebatch, Annie
dc.contributor.authorHill, Anthony
dc.contributor.authorShang, Rong
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-10T22:58:29Z
dc.date.issued2010
dc.date.updated2016-02-24T10:44:16Z
dc.description.abstractThe successive reactions of [Mo(≡CBr)(CO)2(Tp*)] (1; Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with nBuLi and N,N′-dimethylthiocarbamoyl chloride provides as intended, via formation of [Mo(≡CLi)(CO)2(Tp*)] (2a), the thiocarbamoyl alkylidyne c
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/60877
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Alkylidynes; Anhydrous conditions; CBr; Electrophiles; Exchange protocols; Proton donors; Side products; Single electron; Templeton; Chlorine compounds; Spheres; Synthesis (chemical); Molybdenum compounds
dc.titleSynthesis of a thiocarbamoyl alkylidyne complex and caveats associated with the use of [Mo(≡CLi)(CO) 2 (Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate)
dc.typeJournal article
local.bibliographicCitation.issue23
local.bibliographicCitation.lastpage6487
local.bibliographicCitation.startpage6482
local.contributor.affiliationColebatch, Annie, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationShang, Rong, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidColebatch, Annie, u4213195
local.contributor.authoruidHill, Anthony, u4030185
local.contributor.authoruidShang, Rong, u4469159
local.contributor.authoruidWillis, Anthony, u8512028
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationU4217927xPUB570
local.identifier.citationvolume29
local.identifier.doi10.1021/om1008296
local.identifier.scopusID2-s2.0-78649810874
local.identifier.thomsonID000284866000040
local.type.statusPublished Version

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