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Synthesis of α-cyclodextrin [2]-rotaxanes using chlorotriazine capping reagents

Date

Authors

Dawson, Ryan

Maniam, Subashani

Lincoln, Stephen F

Easton, Christopher

Publisher

Royal Society of Chemistry

Abstract

Ten α-cyclodextrin [2]-rotaxanes have been prepared with alkane-, stilbene- and azobenzene-based axles, capped through nucleophilic substitution of either 2-chloro-4,6-dimethoxy-1,3,5-triazine or 2,4-dichloro-6-methoxy-1,3,5- triazine in aqueous solution

Keywords

Keywords: Azobenzene; Derivatives; Dimers; Paraffins; Reaction kinetics; Synthesis (chemical); Capping reagent; Hermaphroditic cyclic dimers; Molecular shuttle; Nucleophilic substitution; Cyclodextrins

URI

http://hdl.handle.net/1885/51250

Collections

ANU Research Publications

Source

Organic and Biomolecular Chemistry

Type

Journal article

DOI

10.1039/b802229a

Restricted until

2037-12-31

Downloads

File

Description

01_Dawson_Synthesis_of_α-cyclodextrin_2008.pdf (226.54 KB)