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Insertion reactions of unsymmetrical ester-activated alkynes with o -benzylamine palladacycles: A regioselectivity study.

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dc.contributor.authorKelly, Amy
dc.contributor.authorMacgregor, Stuart A
dc.contributor.authorWillis, Anthony
dc.contributor.authorNelson, John H
dc.contributor.authorWenger, Eric
dc.date.accessioned2015-12-13T23:39:56Z
dc.date.available2015-12-13T23:39:56Z
dc.date.issued2003
dc.date.updated2015-12-12T09:27:15Z
dc.description.abstractThe regioselectivities of the insertion reactions of RC≡CCO2Et (R=Ph, CF3) into the aryl-palladium bond of several five-membered, ortho-palladated dimethylbenzylamine complexes, [PdCl(C6H4CH2NMe2-κC,N)] 2 (1), [PdCl(C6H4CH2NMe2-κC,N)(L)] [L=PEt3 (2),
dc.identifier.issn0020-1693
dc.identifier.urihttp://hdl.handle.net/1885/94246
dc.publisherElsevier
dc.sourceInorganica Chimica Acta
dc.subjectKeywords: alkyne; benzylamine derivative; carboxylic acid derivative; ester; palladium; polycyclic aromatic hydrocarbon derivative; article; carbon nuclear magnetic resonance; chemical bond; chemical reaction; chemical structure; nuclear magnetic resonance spectros Alkyne insertion; DFT calculation; Dimethylbenzylamine; NMR spectroscopy; Palladacycles; Regiochemistry
dc.titleInsertion reactions of unsymmetrical ester-activated alkynes with o -benzylamine palladacycles: A regioselectivity study.
dc.typeJournal article
local.bibliographicCitation.lastpage97
local.bibliographicCitation.startpage79
local.contributor.affiliationKelly, Amy, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationMacgregor, Stuart A, Heriot-Watt University
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationNelson, John H, University of Nevada
local.contributor.affiliationWenger, Eric, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidKelly, Amy, u3088871
local.contributor.authoruidWillis, Anthony, u8512028
local.contributor.authoruidWenger, Eric, u9205509
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.ariespublicationMigratedxPub23782
local.identifier.citationvolume352
local.identifier.doi10.1016/S0020-1693(03)00149-X
local.identifier.scopusID2-s2.0-0042201871
local.type.statusPublished Version

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