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The curious effect of potassium fluoride on glycerol carbonate. How salts can influence the structuredness of organic solvents

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dc.contributor.authorSarri, Filippoen_AU
dc.contributor.authorTatini, Duccio
dc.contributor.authorAmbrosi, Moira
dc.contributor.authorCarretti, Emiliano
dc.contributor.authorNinham, Barry
dc.contributor.authorDei, Luigi
dc.contributor.authorLo Nostro, Pierandrea
dc.date.accessioned2019-01-15T02:22:29Z
dc.date.issued2018-04-01
dc.description.abstractGlycerol carbonate (4-hydroxymethyl-1,3-dioxolan-2-one, shortly GC) is a dense, viscous, water soluble solvent. The high dielectric constant and dipole moment make it a suitable non-aqueous green solvent for several salts in different applications. GC dissolves significant amounts of inorganic salts such as KF. The saturation of GC with KF leads to the formation of a viscous liquid at room temperature. In this paper, we report on conductivity, rheology, differential scanning calorimetry and infrared spectroscopy experiments that indicate the formation of a glassy liquid where GC molecules and KF ion pairs are intercalated in a firm and ordered tridimensional structure, stabilized by hydrogen bonding and strong ion-dipole interactions.en_AU
dc.format.mimetypeapplication/pdfe_AU
dc.identifier.issn0167-7322en_AU
dc.identifier.urihttp://hdl.handle.net/1885/155167
dc.provenancehttp://www.sherpa.ac.uk/romeo/issn/0167-7322/..."Author's post-print on open access repository after an embargo period of 24 months" from SHERPA/RoMEO site (as at 15/01/19). This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/en_AU
dc.publisherElsevieren_AU
dc.rights© 2018 Elsevier B.V.en_AU
dc.rights.licenseCC-BY-NC-ND 4.0 license.en_AU
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en_AU
dc.sourceJournal of Molecular Liquidsen_AU
dc.titleThe curious effect of potassium fluoride on glycerol carbonate. How salts can influence the structuredness of organic solventsen_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Accessen_AU
local.bibliographicCitation.lastpage405en_AU
local.bibliographicCitation.startpage397en_AU
local.contributor.affiliationNinham, B. W., Department of Applied Mathematics, Research School of Physical Sciences and Engineering, The Australian National Universityen_AU
local.contributor.authoruidu7100478en_AU
local.identifier.ariespublicationa383154xPUB9365
local.identifier.citationvolume255en_AU
local.identifier.doi10.1016/j.molliq.2018.01.152en_AU
local.publisher.urlhttps://www.elsevier.com/en-auen_AU
local.type.statusAccepted Versionen_AU

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