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Rhodium-catalyzed hydroformylation of 4-vinylpyridine: 4-ethylpyridine formation via an unusual cleavage of the Rh?C bond by the enolic form of the oxo product.

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dc.contributor.authorLazzaroni, Raffaello
dc.contributor.authorSettambolo, Roberta
dc.contributor.authorCaiazzo, Aldo
dc.contributor.authorBennett, Martin
dc.date.accessioned2015-12-13T22:22:58Z
dc.date.available2015-12-13T22:22:58Z
dc.date.issued2002
dc.date.updated2015-12-11T08:01:33Z
dc.description.abstractThe hydroformylation of 4-vinylpyridine (4VP) with rhodium catalyst Rh4(CO)12 modified with phosphine ligands (PMe2Ph) is not completely chemoselective to the branched aldehyde 2-(4-pyridyl)propanal (4α), the corresponding hydrogenation product 4-ethylpy
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/72536
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Catalysis; Chemical bonds; Hydrogenation; Nuclear magnetic resonance spectroscopy; Rhodium compounds; Substrates; Catalyst concentration; Organometallics
dc.titleRhodium-catalyzed hydroformylation of 4-vinylpyridine: 4-ethylpyridine formation via an unusual cleavage of the Rh?C bond by the enolic form of the oxo product.
dc.typeJournal article
local.bibliographicCitation.lastpage2459
local.bibliographicCitation.startpage2454
local.contributor.affiliationLazzaroni, Raffaello, Universita degli Studi di Pisa
local.contributor.affiliationSettambolo, Roberta, National Research Council (CNR)
local.contributor.affiliationCaiazzo, Aldo, National Research Council (CNR)
local.contributor.affiliationBennett, Martin, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidBennett, Martin, u6700468
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationMigratedxPub3296
local.identifier.citationvolume21
local.identifier.doi10.1021/om0105371
local.identifier.scopusID2-s2.0-0038236656
local.type.statusPublished Version

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