Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Hybrids of gold nanoparticles and oligo(p-phenyleneethynylene)s end-functionalized with alkynylruthenium groups: Outstanding two-photon absorption in the second biological window

Simple item page
dc.contributor.authorQuintana, Cristóbal
dc.contributor.authorMorshedi, Mahbod
dc.contributor.authorDu, Jun
dc.contributor.authorMorrall, Joseph P. L.
dc.contributor.authorZaręba, Jan K.
dc.contributor.authorSamoc, Marek
dc.contributor.authorCifuentes, Marie P.
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2021-11-08T04:05:56Z
dc.date.available2021-11-08T04:05:56Z
dc.date.issued2020-07-16
dc.description.abstractOligo(p-phenyleneethynylene)s (OPEs) end-capped with (alkynyl)bis(diphosphine)ruthenium and thiol/thiolate groups stabilize ca. 2 nm diameter gold nanoparticles (AuNPs). The morphology, elemental composition and stability of the resultant organometallic OPE/AuNP hybrid materials have been defined using a combination of molecular- and nano-material chacterization techniques. The hybrids display long-term stability in solution (more than a month), good solubility in organic solvents, reversible ruthenium-centered oxidation, and transparency beyond 800 nm, and possess very strong nonlinear absorption activity at the first biological window, and unprecedented two-photon absorption activity in the second biological window (σ2 up to 38,000 GM at 1,050 nm).en_AU
dc.description.sponsorshipWe thank the Australian Research Council (DP170100411: M. G. H. and M. S.) and the National Science Centre (NCN) Poland (UMO-2016/22/M/ST4/00275: J. K. Z. and M. S.) for support of this work. C. Q. thanks Becas Chile (Agencia Nacional de Investigación y Desarrollo) for financial support in the form of a PhD scholarship (2015-72160061), J. P. L. M. thanks the Australian Government for an Australian Postgraduate Award, J. D. thanks the China Scholarship Council and the Australian National University for a CSC-ANU scholarship, and J. K. Z. thanks the Foundation for Polish Science (FNP) for support. The authors acknowledge the facilities, and the scientific and technical assistance, of the Australian Microscopy & Microanalysis Research Facility and the Centre of Advanced Microscopy at the Australian National University.en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn1998-0124en_AU
dc.identifier.urihttp://hdl.handle.net/1885/251643
dc.language.isoen_AUen_AU
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/16476..."The Accepted Version can be archived in a Non-Commercial Institutional Repository. 12 months embargo" from SHERPA/RoMEO site (as at 8/11/2021).en_AU
dc.publisherSpringer Verlagen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP170100411en_AU
dc.rights© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020en_AU
dc.sourceNano Researchen_AU
dc.subjectgold nanoparticlesen_AU
dc.subjectinorganic materialsen_AU
dc.subjectmetal alkynyl complexesen_AU
dc.subjectnonlinear opticsen_AU
dc.subjectorganometallicsen_AU
dc.titleHybrids of gold nanoparticles and oligo(p-phenyleneethynylene)s end-functionalized with alkynylruthenium groups: Outstanding two-photon absorption in the second biological windowen_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Accessen_AU
local.bibliographicCitation.issue10en_AU
local.bibliographicCitation.lastpage2762en_AU
local.bibliographicCitation.startpage2755en_AU
local.contributor.affiliationMorshedi, M., Research School of Chemistry, The Australian National Universityen_AU
local.contributor.affiliationJun, Du, Research School of Chemistry, The Australian National Universityen_AU
local.contributor.affiliationHumphrey, M.Research School of Chemistry, The Australian National Universityen_AU
local.contributor.authoruidu9400918en_AU
local.identifier.ariespublicationa383154xPUB15295
local.identifier.citationvolume13en_AU
local.identifier.doi10.1007/s12274-020-2924-4en_AU
local.publisher.urlhttps://link.springer.com/en_AU
local.type.statusAccepted Versionen_AU

Downloads

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
Hybrids of gold nanoparticles_AAM.pdf
Size:
1.49 MB
Format:
Adobe Portable Document Format
Description:
Download

License bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
884 B
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

ANU Research Publications

DSpace software copyright © 2002-2026 LYRASIS