Facile C-H bond activation: synthesis of the N 4 C donor set pentadentate ligand 1,4-bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) and a structural study of its alkyl?cobalt(III) complex [Co(dmpdacn- C )(OH 2 )](ClO 4 ) 2 ⋅H 2 O and its hydroxylated derivative [Co(dmpdacnOH- O )Cl](ClO 4 ) 2 ⋅C 3 H 6 O
dc.contributor.author | Zhou, Xiangting | |
dc.contributor.author | Day, Anthony | |
dc.contributor.author | Edwards, Alison | |
dc.contributor.author | Willis, Anthony | |
dc.contributor.author | Jackson, William Gregory | |
dc.date.accessioned | 2015-12-13T22:55:16Z | |
dc.date.issued | 2005 | |
dc.date.updated | 2015-12-11T11:09:25Z | |
dc.description.abstract | The 1,4-bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) ligand with a N4C donor set deprotonates at a CH2 γ to an amine under extraordinarily mild conditions (pH 7) and binds as a pentadentate ligand to Co(III) as the [Co(dmpdacn-C)(OH2)]2+ complex. | |
dc.identifier.issn | 0020-1669 | |
dc.identifier.uri | http://hdl.handle.net/1885/82456 | |
dc.publisher | American Chemical Society | |
dc.source | Inorganic Chemistry | |
dc.subject | Keywords: 1,4 bis(2 pyridylmethyl) 1,4 diazacyclononane; amine; chloride; cobalt complex; ligand; pyridine derivative; unclassified drug; article; chemical bond; drug hydroxylation; hydrolysis kinetics; nuclear magnetic resonance; oxidation; synthesis; X ray crysta | |
dc.title | Facile C-H bond activation: synthesis of the N 4 C donor set pentadentate ligand 1,4-bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) and a structural study of its alkyl?cobalt(III) complex [Co(dmpdacn- C )(OH 2 )](ClO 4 ) 2 ⋅H 2 O and its hydroxylated derivative [Co(dmpdacnOH- O )Cl](ClO 4 ) 2 ⋅C 3 H 6 O | |
dc.type | Journal article | |
local.bibliographicCitation.issue | 2 | |
local.bibliographicCitation.lastpage | 460 | |
local.bibliographicCitation.startpage | 452 | |
local.contributor.affiliation | Zhou, Xiangting, University of New South Wales | |
local.contributor.affiliation | Day, Anthony, University of New South Wales | |
local.contributor.affiliation | Edwards, Alison, College of Physical and Mathematical Sciences, ANU | |
local.contributor.affiliation | Willis, Anthony, College of Physical and Mathematical Sciences, ANU | |
local.contributor.affiliation | Jackson, William Gregory, University of New South Wales, ADFA | |
local.contributor.authoremail | u8512028@anu.edu.au | |
local.contributor.authoruid | Edwards, Alison, u9900186 | |
local.contributor.authoruid | Willis, Anthony, u8512028 | |
local.description.embargo | 2037-12-31 | |
local.description.notes | Imported from ARIES | |
local.description.refereed | Yes | |
local.identifier.absfor | 030207 - Transition Metal Chemistry | |
local.identifier.absfor | 030606 - Structural Chemistry and Spectroscopy | |
local.identifier.ariespublication | MigratedxPub10707 | |
local.identifier.citationvolume | 44 | |
local.identifier.doi | 10.1021/ic040081q | |
local.identifier.scopusID | 2-s2.0-12344272889 | |
local.identifier.uidSubmittedBy | Migrated | |
local.type.status | Published Version |
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