Polyazolyl chelate chemistry. 12. An unusual mode of coordination for the hydrotris(methimazolyl)borato ligand
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Foreman, Mark
Hill, Anthony
Owen, Gareth
White, Andrew G
Williams, David
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American Chemical Society
Abstract
The reactions of [RuHCl(CO)(PPh3)3] or [RuH(NCMe)2(CO)(PPh3)2]ClO4 with Na[HB(mt)3] (mt = methimazolyl) provide the structurally characterized complex [RuH(CO)(PPh3){κ3-H,S,S″-HB(mt)3}], which hydrogenates ethynylbenzene to styrene with formation of th
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Organometallics