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A heterobimetallic cumulenic μ-carbido complex

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dc.contributor.authorHill, Anthony
dc.contributor.authorWatson, Lachlan
dc.date.accessioned2020-09-03T01:24:32Z
dc.date.issued2020
dc.date.updated2020-05-17T08:20:12Z
dc.description.abstractThe reaction [W(CSe)(CO)2(Tp*)]NEt4 (Tp* = hydrotris(dimethylpyrazolyl)-borate) with N-methyl-N-nitroso-4-toluenesulfonamide affords the nitrosyl complex [W(CSe)(CO)(NO)(Tp*)] which on treatment with excess [Re(THF)(CO)2(g-C5H5)] affords the cumuenic l-carbido complex [WRe(l-C)(CO)3(NO)(Tp*)(g-C5H5)] in addition to the l-selenido complex [Re2(l-Se)(CO)4(g-C5H5)2].en_AU
dc.description.sponsorshipWe gratefully acknowledge the Australian Research Council (DP170102695 and DP190100723) for funding.en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn1359-7345en_AU
dc.identifier.urihttp://hdl.handle.net/1885/209274
dc.language.isoen_AUen_AU
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/1320..."The Accepted Version can be archived in a Non-Commercial Institutional Repository. 12 months embargo" from SHERPA/RoMEO site (as at 14/12/2020).
dc.publisherRoyal Society of Chemistryen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP170102695en_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP190100723en_AU
dc.rights© 2020 The Royal Society of Chemistryen_AU
dc.sourceChemical Communicationsen_AU
dc.titleA heterobimetallic cumulenic μ-carbido complexen_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Access
local.bibliographicCitation.issue15en_AU
local.bibliographicCitation.lastpage2359en_AU
local.bibliographicCitation.startpage2356en_AU
local.contributor.affiliationHill, Anthony, College of Science, ANUen_AU
local.contributor.affiliationWatson, Lachlan, College of Science, ANUen_AU
local.contributor.authoruidHill, Anthony, u4030185en_AU
local.contributor.authoruidWatson, Lachlan, u5643251en_AU
local.description.notesImported from ARIESen_AU
local.identifier.absfor039904 - Organometallic Chemistryen_AU
local.identifier.absfor030207 - Transition Metal Chemistryen_AU
local.identifier.absfor030204 - Main Group Metal Chemistryen_AU
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciencesen_AU
local.identifier.absseo970102 - Expanding Knowledge in the Physical Sciencesen_AU
local.identifier.ariespublicationa383154xPUB10756en_AU
local.identifier.citationvolume56en_AU
local.identifier.doi10.1039/c9cc08172ken_AU
local.publisher.urlhttp://pubs.rsc.org/en/Journals/JournalIssues/CCen_AU
local.type.statusAccepted Versionen_AU

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