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Optical observation of the 3sσgF³Πu Rydberg state of N₂

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dc.contributor.authorSprengers, J. Pen_AU
dc.contributor.authorReinhold, Een_AU
dc.contributor.authorUbachs, Wen_AU
dc.contributor.authorLewis, B. Ren_AU
dc.contributor.authorBaldwin, Kennethen_AU
dc.date.accessioned2015-10-01T01:49:53Z
dc.date.available2015-10-01T01:49:53Z
dc.date.created13/10/2005en_AU
dc.date.updated2015-12-11T11:12:55Z
dc.description.abstractUsing ultrahigh-resolution 1 XUV+1 UV two-photon ionization laser spectroscopy, the F (3)Pi(u)<--X (1)Sigma(g) (+)(0,0) transition of N(2) has been optically observed for the first time, and the 3s sigma(g)F (3)Pi(u)(upsilon=0) Rydberg level fully characterized with rotational resolution. The experimental spectroscopic parameters and predissociation level widths suggest strong interactions between the F state and the 3p pi(u)G (3)Pi(u) Rydberg and C(') (3)Pi(u) valence states, analogous to those well known in the case of the isoconfigurational (1)Pi(u) states.
dc.description.sponsorshipThe Molecular Atmospheric Physics MAP Program of the Netherlands Foundation for Fundamental Research on Matter FOM, and the Discovery Program of the Australian Research Council are gratefully acknowledged for their support.en_AU
dc.format.extent1 vol.en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn0021-9606en_AU
dc.identifier.urihttp://hdl.handle.net/1885/15744
dc.language.isoen_AUen_AU
dc.publisherAmerican Institute of Physicsen_AU
dc.sourceThe Journal of Chemical Physicsen_AU
dc.subjectKeywords: Rotational resolution; Rydberg state; Ulrahigh resolution; Valence states; Dissociation; Spectroscopic analysis; Photoionizationen_AU
dc.titleOptical observation of the 3sσgF³Πu Rydberg state of N₂en_AU
dc.typeJournal articleen_AU
local.bibliographicCitation.issue14en_AU
local.bibliographicCitation.startpage144315en_AU
local.contributor.affiliationSprengers, J P, Free University Amsterdam , Netherlandsen_AU
local.contributor.affiliationReinhold, E., Free University Amsterdam, Netherlandsen_AU
local.contributor.affiliationUbachs, Wim, Vrije Universiteit (Free University) , Netherlandsen_AU
local.contributor.affiliationBaldwin, Kenneth, College of Physical and Mathematical Sciences, CPMS Research School of Physics and Engineering, Atomic and Molecular Physics Laboratories, The Australian National Universityen_AU
local.contributor.affiliationLewis, Brenton, College of Physical and Mathematical Sciences, CPMS Research School of Physics and Engineering, Atomic and Molecular Physics Laboratories, The Australian National Universityen_AU
local.contributor.authoruidu8413914en_AU
local.description.notesImported from ARIESen_AU
local.description.refereedYes
local.identifier.absfor020201 - Atomic and Molecular Physicsen_AU
local.identifier.ariespublicationMigratedxPub10915en_AU
local.identifier.citationvolume123en_AU
local.identifier.doi10.1063/1.2062189en_AU
local.identifier.scopusID2-s2.0-26944484721
local.publisher.urlhttps://www.aip.org/en_AU
local.type.statusPublished Versionen_AU

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