Ruthenium cluster chemistry: monodentate bis(diphenylphosphino)acetylene-ligated cluster modules in chain and dendrimer formation

Viau, Lydie; Willis, Anthony; Humphrey, Mark

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Ruthenium cluster chemistry: monodentate bis(diphenylphosphino)acetylene-ligated cluster modules in chain and dendrimer formation

Date

2007

Authors

Viau, Lydie

Willis, Anthony

Humphrey, Mark

Publisher

Elsevier

Abstract

Reaction of Ru3(μ-dppm)(CO)10 [dppm = bis(diphenylphosphino)methane] with one equivalent of dppa [dppa = bis(diphenylphosphino)acetylene] afforded Ru3(μ-dppm)(CO)9(η1-dppa) which possesses a monodentate dppa ligand,an X-ray structural study revealing t